Your first session on DJ Neko stays random
The 8 free spins start at random, so no figure tells you how often DJ Neko reaches them. Each MONEY symbol can trigger the bonus, and no session comes with a promised hit. The result of one session stays random whatever the RTP, because the RTP describes only the long run.
96.50 is the RTP version listed for DJ Neko. The version running here is shown only in the game rules, so check that line before you play. The figure describes the return over a very long run, not the outcome of one session.
5,000x the bet is the ceiling for a single win on DJ Neko, and it is reached very rarely. Read that figure as an upper limit, not an average or an expectation. Nothing in the game lets you plan a session around reaching it.